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Quantum simulation of the yellow emission band of CsXeQuantum spectral simulations of the yellow excimer emission band of CsXe are presented. Synthetic spectra as a function of wave number are calculated for the 2 Sigma 1/2 + (7s) - 2 Sigma 1/2 + (6s) transition by the use of the equation of Tellinghuisen et al. (1976) with a theoretical potential for the ground state and a Morse potential curve with an electron frequency of 32/cm for the excited state. Results based on emission studies at 450 K and 200 and 800 torr, are found to be consistent with absorption studies. The undulatory structure observed in the spectrum is attributed not to the vibrational spacing in the excited state, but rather to a characteristic reflection structure associated with nearly parallel upper and lower potential curves.
Document ID
19810034396
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Tellinghuisen, J.
(Vanderbilt University Nashville, Tenn., United States)
Exton, R. J.
(NASA Langley Research Center Instrument Research Div., Hampton, Va., United States)
Date Acquired
August 11, 2013
Publication Date
December 28, 1980
Publication Information
Publication: Journal of Physics B - Atomic and Molecular Physics
Volume: 13
Subject Category
Nuclear And High-Energy Physics
Accession Number
81A18800
Distribution Limits
Public
Copyright
Other

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