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The temperature dependence of the rate constant for the reaction of hydroxyl radicals with nitric acidThe rate constant for the reaction of hydroxyl radicals with nitric acid in the 225-443 K temperature range has been measured by means of the flash photolysis resonance fluorescence technique. Above 300 K, the rate constant levels off in a way that can only be explained by the occurrence of two reaction channels, of which one, operative at low temperatures, proceeds through the formation of an adduct intermediate. The implications of these rate constant values for stratospheric reaction constants is discussed.
Document ID
19820047544
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Kurylo, M. J.
(National Bureau of Standards Washington, DC, United States)
Cornett, K. D.
(National Bureau of Standards Washington, DC, United States)
Murphy, J. L.
(National Bureau of Standards, Chemical Kinetics Div., Washington DC, United States)
Date Acquired
August 10, 2013
Publication Date
April 20, 1982
Publication Information
Publication: Journal of Geophysical Research
Volume: 87
Subject Category
Geophysics
Accession Number
82A31079
Distribution Limits
Public
Copyright
Other

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