Origin of rims on coarse-grained inclusions in the Allende meteorite

Coarse-grained, calcium-rich inclusions in the Allende meteorite are enclosed by sequences of very thin, mineralogically distinct rim layers. A number of questions arise in connection with the presence of rims. The present investigation presents new observations bearing on all these questions and provides a model for the formation of rims. A zoned alteration vein is considered along with a sinuous inclusion, a spinel-perovskite-melilite band (SP), layers overlying the melilite-rich side of SP, a layer overlying the spinel-rich side of SP, and aspects of rim composition and the degree of alteration in coarse-grained inclusions. It is proposed that rims on coarse-grained inclusions formed in a nonequilibrium process involving those reactions between coarse-grained melilite and spinel and a nebular gas phase which also produced the secondary alteration products in the interiors of these inclusions.