Ultraviolet spectroscopy of comae

Vacuum ultraviolet observations from sounding rockets and satellite observatories of the gaseous comae of several recent comets are reviewed. The earliest of these led to discovery of the hydrogen envelope extending for millions of km from the nucleus. Subsequent observations of H I Lyman alpha, the OH (0,0) band and the oxygen resonance triplet have provided strong evidence for the water-ice model of the cometary nucleus. Several new species were discovered in the coma, including C, C(+), CO, S and CS. High-resolution spectroscopy and the spatial variation of the observed emissions provide means to elucidate the production and excitation mechanisms of these species. The similarity of the spectra of the half-dozen comets observed to date argues for a common, homogeneous composition (with the exception of dust and CO) of the cometary ice and a minimal effect on the neutral species due to molecular collisions in the inner coma.