Evaluation of upwelling infrared radiance in a nonequilibrium nonhomogeneous atmosphere

The influence of vibrational nonequilibrium upon upwelling infrared radiance from the earth's atmosphere is investigated. By employing the line-by-line model for spectral absorption, heating rates and upwelling radiances are calculated for equilibrium and nonequilibrium conditions in the spectral range of 4.7 micron CO and 3.3 micron CH4 bands. Heating rates are calculated also for the 15 micron CO2 band and are compared with other available results in the literature. For the spectral range of the CO fundamental band, the influence of different parameters on the upwelling radiance is investigated. It is found that for CO the assumption of local thermodynamic equilibrium (LTE) is not justified at tropospheric temperatures and pressures. If the resonance effects of CO-N2 collisions are considered, then the assumption of LTE is justified up to 60 kilometers. This information is very useful for measurement of atmospheric pollutants, earth radiation budget studies and climate modeling, and infrared signature works.