Capillary rise, wetting layers, and critical phenomena in confined geometry

Interferometric procedures have been used to measure the thickness of the wetting layers of liquid SF6 which intrude between SF6 vapor and the walls of an interferometer. Close to the critical temperature the measurements show that the layers become thicker as the height at which they are observed approaches the height of the bulk liquid-vapor meniscus. The functional form of the thickness increase agrees with the dependence expected from models in which the layers' thicknesses are governed by a competition between gravitational and van der Waals forces. The layers are a factor of three thicker than a simple estimate based on such models. No evidence is found of a transition from three-dimensional critical behavior towards two-dimensional critical behavior in the available temperature and size ranges. This contrasts with the interpretation of experiments in binary liquid mixtures carried out with comparable size and temperature resolution.