Rare earth chalcogenide stoichiometry determinationRare earth chalcogenides, and particularly lanthanum sulfide, are currently explored as candidate materials for thermoelectric applications. Since the electrical properties of LaS(x) are largely determined by its stoichiometry, a simple and accurate method has been developed for determining the value of x. The procedure involves dissolving a weighted sample in acid and measuring the amount of hydrogen evolved by the lanthanum that is in excess of the 1.500 ratio of S/La. The analytical error in the determination of x in LaS(x) is about 0.001.
Document ID
19840047257
Acquisition Source
Legacy CDMS
Document Type
Conference Paper
Authors
Lockwood, R. A. (California Institute of Technology, Jet Propulsion Laboratory, Pasadena CA, United States)