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Gated photochemical hole burning in photoadducts of polyacenesA photoadduct of anthracene and tetracene (A-T) in a polymer matrix at 1.5 K generates an absorption spectrum which exhibits two-color, photon-gated photochemical hole burning (PHB) when irradiated with narrowband exciting light into the 0-0 band of the S1-S0 absorption. The efficiency of this PHB process is found to be enhanced by simultaneous irradiation near the maximum of the Tn-T1 absorption of A-T; hole widths of less than 0.07/cm have been observed for this photochemical cleavage of A-T.
Document ID
19870033877
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Iannone, Mark
(California Univ. Riverside, CA, United States)
Scott, Gary W.
(California, University Riverside, United States)
Brinza, David
(California Univ. Riverside, CA, United States)
Coulter, Daniel R.
(California Institute of Technology Jet Propulsion Laboratory, Pasadena, United States)
Date Acquired
August 13, 2013
Publication Date
November 1, 1986
Publication Information
Publication: Journal of Chemical Physics
Volume: 85
ISSN: 0021-9606
Subject Category
Inorganic And Physical Chemistry
Accession Number
87A21151
Funding Number(s)
CONTRACT_GRANT: NAS7-918
Distribution Limits
Public
Copyright
Other

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