Adiabatic criteria for outer-sphere bimolecular electron-transfer reactions

A model is presented for outer-sphere bimolecular electron-transfer reactions which is correct in the adiabatic, nonadiabatic, and intermediate dynamical regimes for an overdamped solvent coordinate. From this model, the conditions for the transfer to be adiabatic or nonadiabatic are deduced. The time-scale separations needed to adequately describe the process as an average over (distant dependent) unimolecular rates are described.