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Connection between energy relations of solids and moleculesThe universal energy relation, discovered for metallic and covalent solids as well as nuclear matter, is tested for diatomic molecules. It is found that it applies well to covalent diatomic bonds, but that ionic diatomic bonds are in a distinct class. A simple extension of the universal binding energy relation that includes the effects of ionicity ensues. It yields accurate prediction of spectroscopic data for both ionic and covalent bonds in 150 molecules. The form of the covalent part is given by the universal relation, suggesting an intimate relationship between the energetics of solids and diatomic molecules.
Document ID
19890039035
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Smith, John R.
(GM Research Laboratories Warren, MI, United States)
Schlosser, Herbert
(Cleveland State University OH, United States)
Leaf, William
(Harvard University Cambridge, MA, United States)
Ferrante, John
(NASA Lewis Research Center Cleveland, OH, United States)
Rose, James H.
(DOE Ames Laboratory, IA, United States)
Date Acquired
August 14, 2013
Publication Date
January 15, 1989
Publication Information
Publication: Physical Review A - General Physics, 3rd Series
Volume: 39
ISSN: 0556-2791
Subject Category
Inorganic And Physical Chemistry
Accession Number
89A26406
Funding Number(s)
CONTRACT_GRANT: W-7405-ENG-82
Distribution Limits
Public
Copyright
Other

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