The critical complex in nucleation is not the nucleus

A theory of nucleation is presented which combines features of classical nucleation. In this theory, the nucleus is a cluster of finite size with a sharp interface and spinodal decomposition, in which a fluctuation in density or composition generates the critical complex and nucleus. Thus, the nucleus is a product of nucleation. Schematic models for the classical and the proposed routes to nucleation are compared, focusing on the relation between pressure and volume in the models. In the proposed model, the critical complex, or critical state, is between the parent state and the nucleus.