Translation-vibration-dissociation coupling in nonequilibrium hypersonic flows

A new simple and computationally efficient model was developed, describing the evolution of vibrational states during relaxation and dissociation. The model is based on dividing the nitrogen molecules into two types, those in the vibrational states at a lower level, whose vibrational energy is below a cutoff energy, and those in an upper level, with vibrational energy above the cutoff. Dissociation occurs at the upper level, and recombination returns molecules to the lower level. The model was applied to two flows of engineering interest, the flow through a normal Mach 15 shock wave at 60 km, and a supersonic quasi-one-dimensional flow in a nozzle. Results are compared to those obtained by existing translation-vibration-dissociation coupling models, with results indicating significant differences between the models.