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On the electron affinity of Au3The EA of Au3 is estimated to be 3.93 eV. The calculations also show that the feature in the photodetachment spectrum at about 2 eV electron binding energy is due to a two-photon process involving fragmentation of Au3(-) to Au and Au2(-) and subsequent photodetachment of Au2(-). Au3 is found to have a 2B2 ground state that is only slightly distorted from an equilateral triangle.
Document ID
19890057859
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
doi:10.1016/0009-2614(89)87088-5
Authors
Bauschlicher, Charles W., Jr. (NASA Ames Research Center Moffett Field, CA, United States)
Date Acquired
August 14, 2013
Publication Date
March 24, 1989
Publication Information
Publication: Chemical Physics Letters
Volume: 156
ISSN: 0009-2614
Subject Category
Inorganic And Physical Chemistry
Accession Number
89A45230
Distribution Limits
Public
Copyright
Other

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