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Electronic spectra and photophysics of platinum(II) complexes with alpha-diimine ligands - Solid-state effects. I - Monomers and ligand pi dimersTwo types of emission behavior for Pt(II) complexes containing alpha-diimine ligands have been observed in dilute solution. If the complex also has weak field ligands such as chloride, ligand field (d-d) excited states become the lowest energy excited states. If only strong field ligands are present, a diimine 3(pi-pi/asterisk/) state becomes the lowest. In none of the cases studied did metal-to-ligand charge transfer excited state lie lowest.
Document ID
19890064840
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Miskowski, Vincent M. (California Institute of Technology Jet Propulsion Laboratory, Pasadena, United States)
Houlding, Virginia H. (Allied-Signal, Inc. Morristown, NJ, United States)
Date Acquired
August 14, 2013
Publication Date
January 1, 1989
Publication Information
Publication: Inorganic Chemistry
Volume: 28
ISSN: 0020-1669
Subject Category
INORGANIC AND PHYSICAL CHEMISTRY
Distribution Limits
Public
Copyright
Other