Unidentified infrared features in proto-planetary nebulae

The discovery of an unidentified emission feature at 21 microns in the spectra of three protoplanetary nebulae is reported. These objects show large far infrared excess due to a circumstellar dust envelope surrounding a carbon rich central star. Optical, infrared and radio observations of three cool Infrared Astronomy Satellite sources suggest that they are carbon rich objects. Their low resolution spectra show a broad unidentified emission feature at 21 microns which could originate from the bending mode of a hydrocarbon molecule. The similarity of all three objects suggests that this feature is unlikely to be the result of instrumental effects.