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Kinetics and product studies of the reaction ClO + BrO using flash photolysis-ultraviolet absorptionThe reaction between BrO and ClO was studied over the pressure range 50-700 torr and temperature range 220-400 K, using the flash photolysis-ultraviolet absorption method described by Watson et al. (1979). In order to investigate the mechanism of the BrO + ClO reaction, the product branch reactions Br + Cl2O yielding ClO + BrCl and Cl2O + h(nu) yielding products were examined. The rate constant for the overall reaction and the Arrhenius expression for the Br + Cl2O reaction are given, as well as the quantum yield for the production of atomic oxygen from the Cl2O photolysis.
Document ID
19900029234
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Sander, Stanley P.
(Jet Propulsion Lab., California Inst. of Tech. Pasadena, CA, United States)
Friedl, Randall R.
(JPL Pasadena, CA, United States)
Date Acquired
August 14, 2013
Publication Date
January 1, 1989
Publication Information
Publication: Journal of Physical Chemistry
Volume: 93
Issue: 12, 1
ISSN: 0022-3654
Subject Category
Inorganic And Physical Chemistry
Accession Number
90A16289
Distribution Limits
Public
Copyright
Other

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