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Rates of oxidative weathering on the surface of MarsImplicit in the mnemonic 'MSATT' (Mars surface and atmosphere through time) is that rates of surface processes on Mars through time should be investigated, including studies of the kinetics and mechanism of oxidative weathering reactions occurring in the Martian regolith. Such measurements are described. Two major elements analyzed in the Viking Lander XRF experiment that are most vulnerable to atmospheric oxidation are iron and sulfur. Originally, they occurred as Fe(2+)-bearing silicate and sulfide minerals in basaltic rocks on the surface of Mars. However, chemical weathering reactions through time have produced ferric- and sulfate-bearing assemblages now visible in the Martian regolith. Such observations raise several question about: (1) when the oxidative weathering reactions took place on Mars; (2) whether or not the oxidized regolith is a fossilized remnant of past weathering processes; (3) deducting chemical interactions of the ancient Martian atmosphere with its surface from surviving phases; (4) possible weathering reactions still occurring in the frozen regolith; and (5) the kinetics and mechanism of past and present-day oxidative reactions on Mars. These questions may be addressed experimentally by studying reaction rates of dissolution and oxidation of basaltic minerals, and by identifying reaction products forming on the mineral surfaces. Results for the oxidation of pyrrhotite and dissolved ferrous iron are reported.
Document ID
19920019756
Acquisition Source
Legacy CDMS
Document Type
Conference Paper
Authors
Burns, Roger G.
(Massachusetts Inst. of Tech. Cambridge, MA, United States)
Date Acquired
September 6, 2013
Publication Date
January 1, 1992
Publication Information
Publication: Lunar and Planetary Inst., Workshop on the Martian Surface and Atmosphere Through Time
Subject Category
Lunar And Planetary Exploration
Accession Number
92N28999
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
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