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Theoretical study of the bonding of the first- and second-row transition-metal positive ions to acetyleneThe bonding of transition-metal ions to acetylene is studied by using a theoretical treatment that includes electron correlation. The ions on the left side of the first and second transition rows insert into the pi bond to form a three-membered ring. On the right side of the row the bonding is electrostatic. The trends in bonding are discussed.
Document ID
19920051283
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
doi:10.1021/j100175a042
Authors
Sodupe, M. (NASA Ames Research Center Moffett Field, CA, United States)
Bauschlicher, Charles W., Jr. (NASA Ames Research Center Moffett Field, CA, United States)
Date Acquired
August 15, 2013
Publication Date
January 1, 1991
Publication Information
Publication: Journal of Physical Chemistry
Volume: 95
Issue: 22, 1
ISSN: 0022-3654
Subject Category
Inorganic And Physical Chemistry
Accession Number
92A33907
Distribution Limits
Public
Copyright
Other

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