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Kinetics of the reactions of alkyl radicals with HBr and DBrThe kinetics of the reactions CH3 + HBr, CD3 + HBr, CH3 + DBr, C2H5 + HBr, C2H5 + DBr, t-C4H9 + HBr, and t-C4H9 + DBr is studied as a function of temperature (257-430 K) and pressure (10-300 Torr of N2). Time-resolved resonance fluorescence detection of Br atom appearance following laser flash photolysis of RI was used in the experiments. Results show that the rates of all reactions increased as the temperature decreased.
Document ID
19930060531
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Nicovich, J. M.
(NASA Headquarters Washington, DC United States)
Van Dijk, C. A.
(NASA Headquarters Washington, DC United States)
Kreutter, K. D.
(NASA Headquarters Washington, DC United States)
Wine, P. H.
(Georgia Inst. of Technology Atlanta, United States)
Date Acquired
August 16, 2013
Publication Date
January 1, 1991
Publication Information
Publication: Journal of Physical Chemistry
Volume: 95
Issue: 24
ISSN: 0022-3654
Subject Category
Inorganic And Physical Chemistry
Accession Number
93A44528
Funding Number(s)
CONTRACT_GRANT: NSF ATM-88-02386
CONTRACT_GRANT: NSF ATM-91-04807
CONTRACT_GRANT: NAGW-1001
Distribution Limits
Public
Copyright
Other

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