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Rotational structure in the near-infrared absorption spectrum of ozoneThe lowest energy members of the near-IR absorption bands of ozone possess fine structure which is probably due to the rotation of the molecule in the upper vibronic state, suggesting that this state is metastable. A preliminary analysis of the structures as rotational subbands supports a recent theoretical assignment of the near-IR vibronic features to the 3A2 - 1A1 electronic transition. A binding energy of about 0.1 eV is inferred from the breakoff in the observed structure.
Document ID
19930063537
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Anderson, Stuart M.
(Augsburg College Minneapolis, MN, United States)
Hupalo, Peter
(NASA Headquarters Washington, DC United States)
Mauersberger, Konrad
(Minnesota Univ. Minneapolis, United States)
Date Acquired
August 16, 2013
Publication Date
July 1, 1993
Publication Information
Publication: Journal of Chemical Physics
Volume: 99
Issue: 1
ISSN: 0021-9606
Subject Category
Atomic And Molecular Physics
Accession Number
93A47534
Distribution Limits
Public
Copyright
Other

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