Line strength and self-broadening coefficient of the pure rotational S(1) quadrupole line in H2

The absolute intensity, S(sub 1), and self-broadening coefficient, gamma(sub L), for H2 S(sub zero)(1) pure rotational line at 17.0348 micrometers (587.032 cm(exp -1)) have been measured for the first time using a tunable diode laser spectrometer with a resolution of approximately 1 x 10(exp -3) cm(exp -1). By fitting a Galatry line shape convolved with a 1 x 10(exp -3) cm(exp -1) Gaussian instrument profile to absorption profiles, for H2 pressures ranging from 0.34 to 1.30 atm, values of s(sub 1) = (7.0 +/- 0.4) x 10(exp -8) cm(exp -2) atm(exp -1) and gamma(sub L) = (1.73 +/- 0.12) x 10(exp -3) cm(exp -1) atm(exp -1) were obtained.