Constraints placed on the chondrule-forming process by merrihueite in the Mezoe-Madaras chondrite

A few unusual chondrules in the Mezoe-Madaras L3 chondrite contain the peralkaline mineral merrihueite, (K, Na)2(Fe, Mg)5Si12O30, formed by reaction of free silica in the chondrules with K, Na, Fe-rich nebular gas. Vapor fractionation was required to create chondrules poor in Al and rich in Si, and the fractionated condensate produced had to aggregate into protochondrules very promptly (on the order of hours or less) to prevent it from mixing with dust of more generalized composition in the nebula. The traditional paradigm for chondrule formation, involving a series of unrelated events (chemical fractionation of precursor dust; clumping of the dust; melting of the dust-clumps), is inadequate for making these chondrules. A rapid process, all stages of which are related, is required. We propose that this occurred during the cooling and contraction of the volume of hot gas created by a small transient high-energy event in the nebula, of unspecified nature. Microdroplets of silicate melt created by condensation from the cooling, contracting gas had velocity vectors directed toward the center of the volume. Coalescence occurred in the crowded central zone where the microdroplets converged. The Mezoe-Madaras merriihueite-bearing chondrules may have been formed by an atypically low-energy nebular event, which achieved the needed chemical fractionations by only partially vaporizing precursor dust. More commonplace chondrule types may have been created by the same basic process, but involving higher-energy events in which precursor dust was completely vaporized and recondensed.