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Multiple steady states in atmospheric chemistryThe equations describing the distributions and concentrations of trace species are nonlinear and may thus possess more than one solution. This paper develops methods for searching for multiple physical solutions to chemical continuity equations and applies these to subsets of equations describing tropospheric chemistry. The calculations are carried out with a box model and use two basic strategies. The first strategy is a 'search' method. This involves fixing model parameters at specified values, choosing a wide range of initial guesses at a solution, and using a Newton-Raphson technique to determine if different initial points converge to different solutions. The second strategy involves a set of techniques known as homotopy methods. These do not require an initial guess, are globally convergent, and are guaranteed, in principle, to find all solutions of the continuity equations. The first method is efficient but essentially 'hit or miss' in the sense that it cannot guarantee that all solutions which may exist will be found. The second method is computationally burdensome but can, in principle, determine all the solutions of a photochemical system. Multiple solutions have been found for models that contain a basic complement of photochemical reactions involving O(x), HO(x), NO(x), and CH4. In the present calculations, transitions occur between stable branches of a multiple solution set as a control parameter is varied. These transitions are manifestations of hysteresis phenomena in the photochemical system and may be triggered by increasing the NO flux or decreasing the CH4 flux from current mean tropospheric levels.
Document ID
19950039671
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Stewart, Richard W.
(NASA Goddard Space Flight Center Greenbelt, MD, United States)
Date Acquired
August 16, 2013
Publication Date
November 20, 1993
Publication Information
Publication: Journal of Geophysical Research
Volume: 98
Issue: D11
ISSN: 0148-0227
Subject Category
Environment Pollution
Accession Number
95A71270
Distribution Limits
Public
Copyright
Other

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