The abundances of methane and ortho/para hydrogen on Uranus and Neptune: Implications of New Laboratory 4-0 H2 quadrupole line parameters

The tropospheric methane molar fraction (f(sub CH4, t) and the ortho/para hydrogen ratio are derived for Uranus and Neptune based on new determinations of spectroscopic parameters for key hydrogen features as reported by D. W./ Ferguson et al. (1993). For each planet, the relatively weak laboratory linestrengths (approximately 30 and 15% less than the theoretical 4-0 S(0) and S(1) linestrengths, respectively) results, when compared to analyses adopting theroetical values, in a approximately 30% decrease in the tropospheric methane ratio and a comparable increase in the pressure level of the optically thick cloudtop marking the bottom of the visible atmosphere (P(sub c/d)). The increase in the ratio of S(1)/S(0) linestrengths from 4.4 (theoretical) to approximately 5.9 (measured) results in a decrease in the range of viable ortho/para ratios; an equilibrium hydrogen distribution is now the best fit for both planets. The methane mixing ratios reported here are in agreement with the value of 0.023 derived by the Voyager Radio Occultation Experiment (G. F. Lindal, 1992) for Neptune, but slightly lower than the Voyager Uranus measurement of 0.023 reported by G. F. LIndel et al. (1987). The relative carbon-to-hydrogen abundances for Uranus and Neptune support planetary formation mechanisms involving the dissolution of carbon-bearing planetesimals in the atmospheres of both planets during their early stages of formation (e.g., J. B. Pollack et al., 1986).