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Trans-Bis(acetato-o)bis(4-methylpyridine-N)copper(II)The structure of trans-bis(acetato-O)bis(4-methyl- pyridine-N)copper(II), (Cu(C2H302)(sub 2)(C6H7N)(sub 2)), re- ported herein, represents a monomeric parent acetate complex with a distorted square-planar arrangement of acetate and 4-methylpyridine ligands around the Cu atom with the following distances and angles: Cu-N = 2.027 (4) and Cu-O1 = 1.950 (3) A; O1-Cu-N = 89.1 (2) and O1 -Cu-N' = 90.9 (2)deg. The Cu atom resides on a center of inversion. The most important dihedral angles are the angle between the 4-methylpyridine plane and the acetate plane (O1, O2, C21 and C22), 78.2 deg and the angle between the 4-methylpyridine ring and the coordination plane (Cu, N, O1), 31.6 deg.
Document ID
19970016824
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Jedrzejas, Marek J.
(Cleveland State Univ. Cleveland, OH United States)
Towns, Robert L. R.
(Cleveland State Univ. Cleveland, OH United States)
Baker, Ronald J.
(Cleveland State Univ. Cleveland, OH United States)
Duraj, Stan A.
(Cleveland State Univ. Cleveland, OH United States)
Hepp, Aloysius F.
(NASA Lewis Research Center Cleveland, OH United States)
Date Acquired
August 17, 2013
Publication Date
January 1, 1994
Publication Information
Publication: Acta. Crystallographica
Publisher: International Union of Crystallography
Volume: Section C50
ISSN: 0108-2701
Subject Category
Solid-State Physics
Report/Patent Number
NASA-TM-112703
NAS 1.15:112703
Accession Number
97N71532
Distribution Limits
Public
Copyright
Public Use Permitted.
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