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Line Narrowing Parameter Measurement by Modulation SpectroscopyAccurate Characterization of Oxygen A-Band Line Parameters by Wavelength Modulation Spectroscopy with tunable diode lasers is an ongoing research at Old Dominion University, under sponsorship from NASA Langley research Center. The work proposed here will be undertaken under the guidance of Dr. William Chu and Dr. Lamont Poole of the Aerosol Research Branch at NASA Langley-Research Center in Hampton, Virginia. The research was started about two years ago and utilizes wavelength modulation absorption spectroscopy with higher harmonic detection, a technique that we developed at Old Dominion University, to obtain the absorption line characteristics of the Oxygen A-band rovibronic lines. Accurate characterization of this absorption band is needed for processing of data that will be obtained in experiments such as the NASA Stratospheric Aerosol and Gas Experiment III (SAGE III) as part of the US Mission to Planet Earth. The research work for Summer Fellowship undertook a measurement of the Dicke line-narrowing parameters of the Oxygen A-Band lines by using wavelength modulation spectroscopy. Our previous theoretical results had indicated that such a measurement could be done sensitively and in a convenient fashion by using this type of spectroscopy. In particular, theoretical results had indicated that the signal magnitude would depend on pressure in a manner that was very sensitive to the narrowing parameter. One of the major tasks undertaken during the summer of 1998 was to establish experimentally that these theoretical predictions were correct. This was done successfully and the results of the work are being prepared for publication. Experimental Results were obtained in which the magnitude of the signal was measured as a function of pressure, for various harmonic detection orders (N = 1, 2, 3, 4, 5). A comparison with theoretical results was made, and it was shown that the agreement between theory and experiment was very good. More importantly, however, it was shown that the measurement was yielded a very sensitive technique for obtaining the narrowing parameter that describes the deviation of Oxygen A-band lines from the Voigt profile. In particular, it was seen that the best fits were obtained consistently when the narrowing parameter value used was 0.022 1/cm, 1/Atm, Previous work, upon which the current work was based has resulted in several accurate measurements of properties of particular lines of the Oxygen A band. For example, this work has resulted in the measurement of the collision cross sections of several lines including the RQ(13,14) and the RR(15,15) lines. A major achievement of achievement of the work was also the demonstration that the technique we have developed can accurately probe the structure of the absorption lineshape function. In particular, the method we have developed is very well suited for experimentally probing the characteristics of lines in their wings. This work was accepted for publication in the Journal of Applied Physics, and is scheduled to appear in the December 15, 1998 issue.
Document ID
19990019700
Acquisition Source
Langley Research Center
Document Type
Conference Paper
Authors
Dharamsi, Amin N.
(Old Dominion Univ. Norfolk, VA United States)
Date Acquired
August 19, 2013
Publication Date
December 1, 1998
Publication Information
Publication: 1998 NASA-HU American Society for Engineering Education (ASEE) Summer Faculty Fellowship Program
Subject Category
Inorganic And Physical Chemistry
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.

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