An Assessment of the Ozone Loss During the 1999-2000 SOLVE Campaign

Ozone observations from ozonesondes, the DIAL and AROTEL lidars aboard the DC-8, in situ ozone measurements from the ER-2 and satellite ozone measurements from POAM were used to assess ozone loss during the SOLVE 1999-2000 campaign. We compare three different methods of computing the ozone loss. The first method simply compares the time sequence of ozonesondes taken at the same station inside the vortex from December through the end of March. In the second method, ozonesondes from a variety of stations are compared using a variant on the Match technique. This method uses short (approx. 5-10 day) forward diabatic trajectories to connect various sonde launches. In the third method, the measurements are simply injected into a diabatic trajectory model and carried forward in time from December 1 to March 16. Over 60,000 individual measurements were used in the last calculation. Again, ozone loss is estimated by comparing vortex interior measurements made early in the campaign with those made later in the campaign. The diabatic nature of the second and third methods calculation presumably corrects for the normal increase in ozone within the vortex due to downward advection. The three methods agree that the largest ozone loss occurs between 400 and 460 K potential temperatures (approx. 16-20 km) with slightly over 1.5 ppmv lost over the winter period. Between 460 K and 500 K (approx. 22 km) net ozone loss is less than 0.8 ppmv. From 500K to 600K (26 km) net loss is less than 0.5 ppmv.