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Chondrules in the LEW85332 Ungrouped Carbonaceous Chondrite: Fractionation Processes in the Solar NebulaWe studied 14 chondrules separated from LEW85332, an ungrouped type-3 carbonaceous chondrite related to CR chondrites; 23 elements were determined by neutron activation and the chondrules were characterized petrographically. Oxygen isotopic compositions were determined by R. N. Clayton and T. K. Mayeda for seven chondrules. Chondrule abundance ratios tend to form one of two distinct patterns. In low FeO chondrules, refractory lithophile patterns are flat (i.e., unfractionated); siderophile abundances are high and show a small decrease with increasing volatility. Although high FeO chondrules also have flat refractory lithophile abundance patterns, siderophile abundances are highly fractionated; refractory Ir is very low and Fe is very high relative to other siderophiles. We suggest that the low FeO chondrules in LEW85332 formed early in nebular history when metal was intimately mixed with silicates in the chondrule precursors, and that the viscosity of the liquid-solid mix was too high to permit expulsion of the metal by centrifugal action; their porphyritic structures are consistent with incomplete melting, which would result in relatively high viscosities. When the high FeO chondrules formed somewhat later, much of the Fe was oxidized and the melting of precursors was more extensive, FeO and other oxidized siderophiles were retained in the silicate liquid, and metal was lost, possibly expelled from low viscosity chondrule melts. The O isotopic compositions of the chondrules form a linear array of slope 0.93 +/- 0.05 on a three-isotope diagram, parallel to the carbonaceous chondrite anhydrous minerals (CCAM) line and a CR chondrule array, but offset from the latter by -1% in (delta)O-18. Some or all of this offset may reflect incorporation of O from Antarctic water during weathering. Chondrule (Delta)O-17 values correlate positively with FeO, possibly indicating that the (Delta)O-17 of the nebular gas composition increased with time. The chemical and O isotopic data suggest a temporal sequence extending from early, low FeO to late high FeO chondrules.
Document ID
20010071973
Acquisition Source
Headquarters
Document Type
Reprint (Version printed in journal)
Authors
Wasson, John T.
(California Univ. Los Angeles, CA United States)
Kallemeyn, Gregory W.
(California Univ. Los Angeles, CA United States)
Rubin, Alan E.
(California Univ. Los Angeles, CA United States)
Date Acquired
August 20, 2013
Publication Date
January 8, 2000
Publication Information
Publication: Geochimica et Cosmochimica Acta
Publisher: Elsevier Science Ltd.
Volume: 64
Issue: 7
ISSN: 0016-7037
Subject Category
Astrophysics
Funding Number(s)
CONTRACT_GRANT: NASW-2243
Distribution Limits
Public
Copyright
Other

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