The NO Vibrational Fundamental Band: O2-Broadening Coefficients

Rovibrational spectra of the vibrational fundamental of nitric oxide at 1875 cm-1 have been recorded under O2-broadening conditions at 296 K and 0.0056 cm-1 resolution using the Solar Nemeth FTS at the Kitt Peak National Observatory. The use of a flow system, which maintains the NO2 at trace levels, has enabled the first measurement of these broadening coefficients. The broadening of the trace contaminant, N2O, allowed checks of the measured pressures. The least-squares analysis of the spectra includes the nuclear hyperfine structure in addition to (lambda) doubling. We observed differential broadening between the e and f (lambda) components of 2II 1/2 transitions as well as larger differences in broadening observed between 2II3/2 transitions.