Variability in Ozone in the Tropical Tropopause Region from the 1998-2000 SHADOZ (Southern Hemisphere ADditional OZonesondes) Data

The first view of stratospheric and tropospheric ozone variability in the southern hemisphere tropics is provided by a 3-year, 10-site record of ozone soundings from the Southern Hemisphere ADditional OZonesondes (SHADOZ) network. Observations covering 1998-2000 were made over Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Taking the TTL (tropical tropopause layer) as the region between 12 and 17 km, we examine ozone variability in this region on a week-to-week and seasonal basis. The TTL layer is lower in September-October-November than in March-April-May, when ozone is a minimum at most SHADOZ stations. A zonal wave-one pattern is apparent in column-integrated TTL ozone because ozone mixing ratios are greater over the Atlantic and adjacent continents than over the Pacific and eastern Indian Ocean. The wave-one persists all year with varying magnitude and appears to be due to general circulation - with subsidence over the Atlantic and frequent deep convection over the Pacific and Indian Ocean. The variability of deep convection - most prominent at Java, Fiji, Samoa and Natal - is explored in time-vs-altitude ozone curtains. Stratospheric incursions into the troposphere are most prominent in soundings at Irene and Reunion Island.