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Amino acids in the Martian meteorite NakhlaA suite of protein and nonprotein amino acids were detected with high-performance liquid chromatography in the water- and acid-soluble components of an interior fragment of the Martian meteorite Nakhla, which fell in Egypt in 1911. Aspartic and glutamic acids, glycine, alanine, beta-alanine, and gamma-amino-n-butyric acid (gamma-ABA) were the most abundant amino acids detected and were found primarily in the 6 M HCl-hydrolyzed, hot water extract. The concentrations ranged from 20 to 330 parts per billion of bulk meteorite. The amino acid distribution in Nakhla, including the D/L ratios (values range from <0.1 to 0.5), is similar to what is found in bacterially degraded organic matter. The amino acids in Nakhla appear to be derived from terrestrial organic matter that infiltrated the meteorite soon after its fall to Earth, although it is possible that some of the amino acids are endogenous to the meteorite. The rapid amino acid contamination of Martian meteorites after direct exposure to the terrestrial environment has important implications for Mars sample-return missions and the curation of the samples from the time of their delivery to Earth.
Document ID
20040141878
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Glavin, D. P.
(Scripps Institution of Oceanography, University of California at San Diego La Jolla, CA 93093-0212, United States)
Bada, J. L.
Brinton, K. L.
McDonald, G. D.
Date Acquired
August 22, 2013
Publication Date
August 3, 1999
Publication Information
Publication: Proceedings of the National Academy of Sciences of the United States of America
Volume: 96
Issue: 16
ISSN: 0027-8424
Subject Category
Lunar And Planetary Science And Exploration
Report/Patent Number
ISSN: 0027-8424
Distribution Limits
Public
Copyright
Other
Keywords
NASA Discipline Exobiology
Non-NASA Center
Amino Acids/analysis
Mars
Meteoroids
Glutamic Acid/analysis
Glycine/analysis
beta-Alanine/analysis
Support, U.S. Gov't, Non-P.H.S
gamma-Aminobutyric Acid/analysis
Egypt
Aspartic Acid/metabolism
Alanine/analysis

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