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Nanoparticles modified with multiple organic acidsSurface-modified nanoparticles of boehmite, and methods for preparing the same. Aluminum oxyhydroxide nanoparticles are surface modified by reaction with selected amounts of organic acids. In particular, the nanoparticle surface is modified by reactions with two or more different carboxylic acids, at least one of which is an organic carboxylic acid. The product is a surface modified boehmite nanoparticle that has an inorganic aluminum oxyhydroxide core, or part aluminum oxyhydroxide core and a surface-bonded organic shell. Organic carboxylic acids of this invention contain at least one carboxylic acid group and one carbon-hydrogen bond. One embodiment of this invention provides boehmite nanoparticles that have been surface modified with two or more acids one of which additional carries at least one reactive functional group. Another embodiment of this invention provides boehmite nanoparticles that have been surface modified with multiple acids one of which has molecular weight or average molecular weight greater than or equal to 500 Daltons. Yet, another embodiment of this invention provides boehmite nanoparticles that are surface modified with two or more acids one of which is hydrophobic in nature and has solubility in water of less than 15 by weight. The products of the methods of this invention have specific useful properties when used in mixture with liquids, as filler in solids, or as stand-alone entities.
Document ID
20080009467
Acquisition Source
Johnson Space Center
Document Type
Other - Patent
Authors
Cook, Ronald Lee
Luebben, Silvia DeVito
Myers, Andrew William
Smith, Bryan Matthew
Elliott, Brian John
Kreutzer, Cory
Wilson, Carolina
Meiser, Manfred
Date Acquired
August 24, 2013
Publication Date
July 17, 2007
Subject Category
Composite Materials
Funding Number(s)
CONTRACT_GRANT: NAS9-03017
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
Patent
US-Patent-7,244,498
Patent Application
US-Patent-Appl-SN-11/120,650
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