Marangoni Effects on the Bubble Dynamics in a Pressure Driven Flow

The motion of air bubbles and water drops in a Hele-Shaw cell filled with a silicone oil has been studied experimentally and theoretically. By adding a predetermined amount of a surfactant to the water drops we attempted to investigate the surfactant influence systematically. While the motion of air bubbles was in reasonable agreement with the predictions of Taylor and Saffman, water drops behaved quite differently in that the translational velocities were smaller by an order of magnitude and their shapes were very unusual as observed previously by Kopf-Sill and Homsy. Assuming that the surrounding fluid wets the solid wall and the bubble (or the drop) surface is rigid due to the surfactant influence, we have estimated the translational velocity of an elliptic bubble. The calculated velocities were in good agreement with the observations indicating that the surfactant influence could retard the bubble motion significantly. The present study also indicates that the unusual bubble shapes are also due to the surfactant influence.