Demonstration of Robustness and Integrated Operation of a Series-Bosch System

Manned missions beyond low Earth orbit will require highly robust, reliable, and maintainable life support systems that maximize recycling of water and oxygen. Bosch technology is one option to maximize oxygen recovery, in the form of water, from metabolically-produced carbon dioxide (CO2). A two stage approach to Bosch, called Series-Bosch, reduces metabolic CO2 with hydrogen (H2) to produce water and solid carbon using two reactors: a Reverse Water-Gas Shift (RWGS) reactor and a carbon formation (CF) reactor. Previous development efforts demonstrated the stand-alone performance of a RWGS reactor containing Incofoam(TradeMark) catalyst and designed for robustness against carbon formation, two membrane separators intended to maximize single pass conversion of reactants, and a batch CF reactor with both transit and surface catalysts. In the past year, Precision Combustion, Inc. (PCI) developed and delivered a RWGS reactor for testing at NASA. The reactor design was based on their patented Microlith(TradeMark) technology and was first evaluated under a Phase I Small Business Innovative Research (SBIR) effort in 2010. The Microlith(TradeMark) RWGS reactor was recently evaluated at NASA to compare its performance and operating conditions with the Incofoam(TradeMark) RWGS reactor. Separately, in 2015, a fully integrated demonstration of an S-Bosch system was conducted. In an effort to mitigate risk, a second integrated test was conducted to evaluate the effect of membrane failure on a closed-loop Bosch system. Here, we report and discuss the performance and robustness to carbon formation of both RWGS reactors. We report the results of the integrated operation of a Series-Bosch system and we discuss the technology readiness level. 1