Airborne measurements of air pollution chemistry and transport. 1: Initial survey of major air basins in California

An instrumented aircraft has been used to study photochemical air pollution in the State of California. Simultaneous measurements of the most important chemical constituents (ozone, total oxidant, hydrocarbons, and nitrogen oxides, as well as several meteorological variables) were made. State-of-the-art measurement techniques and sampling procedures are discussed. Data from flights over the South Coast Air Basin, the San Francisco Bay Area, the San Joaquin Valley, the Santa Clara and Salinas Valleys, and the Pacific Ocean within 200 miles of the California coast are presented. Pollutants were found to be concentrated in distant layers up to at least 18,000 feet. In many of these layers, the pollutant concentrations were much higher than at ground level. These findings bring into serious question the validity of the present practice of depending solely on data from ground-based monitoring stations for predictive models.