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Reassignment of the Iron (3) Absorption Bands in the Spectra of MarsAbsorption features in the near-infrared and visible region reflectance spectra of Mars have been assigned to specific Fe (3+) crystal-field and o(2-) yields Fe(3+) charge transfer transitions. Recently, near-ultraviolet absorption spectra of iron oxides were obtained and the energies of o(2-) yields Fe(3+) charge-transfer (LMCT) transitions were determined from accurate SCF-X # alpha-SW molecular orbital calculations on (FeO6)(9-) and (FeO4)(5-) clusters. Both the theoretical and experimental results, together with existing data in the literature, show that some of the previous Fe(3+) band assignments in the spectra of Mars need to be revised. The theory of Fe(3+) spectra in minerals is discussed and applied to the spectrum of Mars.
Document ID
19850015303
Document Type
Other
Authors
Sherman, D. M.
(Massachusetts Inst. of Tech. Cambridge, MA, United States)
Date Acquired
August 12, 2013
Publication Date
April 1, 1985
Publication Information
Publication: NASA, Washington Repts. of Planetary Geol. and Geophys. Program, 1984
Subject Category
Lunar And Planetary Exploration
Accession Number
85N23614
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
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