Cryogenic Thermal Coatings Final Report

The goals of this project were to produce yttrium oxide- (Y2O3) based tiles and a spray-on coating
with minimal solar absorption, to perform exposure testing on these coatings (both rigid and sprayon), and to work towards a manufacturing process whereby these coatings could be made available to the space community. The Key Performance Parameters (threshold values) were to achieve 1% solar absorption for the tiles as measured in a deep space simulator, and 6% solar absorption for the spray-on coating as measured using a reflectance spectrometer. The values achieved were 1.2% (GRC Deep space simulator) and 4% (KSC spectrometer using Spectralon as a reference) for the tiles and spray-on coating, respectively. Exposure testing consisted of measuring tile and spray-on coating degradation due to atomic oxygen, ultraviolet radiation, and electrostatic fields. Atomic oxygen caused some degradation, while ultraviolet exposure caused a significant increase in absorption. However, in-space samples exposed to solar ultraviolet did not show this significant increase. This discrepancy is addressed in this report.

As a result of this work, Y2O3 tiles have been manufactured in the Kennedy Space Center (KSC)
Applied Chemistry Laboratory (ACL), and the process has been transferred to the Thermal
Protection System Facility (TPSF) at KSC. The TPSF manufactures coatings for the space
community and is an ideal route by which future users could access Y2O3-based coatings. The
spray-on coating has been developed such that it can be applied to a wide range of substrates,
substantially lowering absorbed solar power as compared to currently available coatings.