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Fe-Ti-Cr-Oxides in Martian Meteorite EETA79001 Studied by Point-counting Procedure Using Raman SpectroscopyFe-Ti-Cr-Oxide minerals contain much information about rock petrogenesis and alteration. Among the most important in the petrology of common intrusive and extrusive rocks are those of the FeO-TiO2-Cr2O3 compositional system chromite, ulv spinel-magnetite, and ilmenite-hematite. These minerals retain memories of oxygen fugacity. Their exsolution into companion mineral pairs give constraints on formation temperature and cooling rate. Laser Raman spectroscopy is anticipated to be a powerful technique for characterization of materials on the surface of Mars. A Mars Microbeam Raman Spectrometer (MMRS) is under development. It combines a micro sized laser beam and an automatic point-counting mechanism, and so can detect minor minerals or weak Raman-scattering phases such as Fe- Ti-Cr-oxides in mixtures (rocks & soils), and provide information on grain size and mineral mode. Most Fe-Ti-Cr-oxides produce weaker Raman signals than those from oxyanionic minerals, e.g. carbonates, sulfates, phosphates, and silicates, partly because most of them are intrinsically weaker Raman scatters, and partly because their dark colors limit the penetration depth of the excitation laser beam (visible wavelength) and of the Raman radiation produced. The purpose of this study is to show how well the Fe-Ti-Cr-oxides can be characterized by on-surface planetary exploration using Raman spectroscopy. We studied the basic Raman features of common examples of these minerals using well-characterized individual mineral grains. The knowledge gained was then used to study the Fe-Ti-Cr-oxides in Martian meteorite EETA79001, especially effects of compositional and structural variations on their Raman features.
Document ID
20030111577
Document Type
Conference Paper
Authors
Wang, Alian (Washington Univ. Saint Louis, MO, United States)
Kuebler, Karla E. (Washington Univ. Saint Louis, MO, United States)
Jolliff, Bradley L. (Washington Univ. Saint Louis, MO, United States)
Haskin, Larry A. (Washington Univ. Saint Louis, MO, United States)
Date Acquired
August 21, 2013
Publication Date
January 1, 2003
Publication Information
Publication: Lunar and Planetary Science XXXIV
Subject Category
Lunar and Planetary Science and Exploration
Funding Number(s)
CONTRACT_GRANT: NAG5-12114
CONTRACT_GRANT: NAG5-10703
Distribution Limits
Public
Copyright
Public Use Permitted.

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