Alumina Size Distributions from High-Pressure Composite Solid-Propellant Combustion

Alumina size distributions were obtained for both a coarse and a fine oxidizer composite propellant burning in a nitrogen atmosphere over the pressure range from atmospheric to 500 pounds per square inch. The amount of additive agglomeration was found to be significantly higher for the coarse oxidizer propellant and decreased with increasing pressure to the 0.3 power over the range from atmospheric pressure to 250 pounds per square inch. High-speed photographs of the burning propellant surface revealed that the additives moved on the surface with the average particle velocity decreasing with pressure to approximately the 0.3 power over the pressure range from atmospheric to 50 pounds per square inch. The empirical relation between particle velocity and pressure was used to modify an agglomeration criterion presented previously. Evaluation of the critical aluminum diameter required for agglomeration indicated that both propellant types used in this study should experience some agglomeration over the pressure range studied. The aluminum size required for agglomeration was found to increase with increasing pressure. The experimental findings of the critical aluminum diameter required for agglomeration were in reasonable agreement with the calculated data. The volume mean diameter of the alumina was found to decrease with increasing pressure.